a novel method for synthesis of substituted naphthofurans and naphthopyrans

Authors

mohammad reza saidi

samad alihoseinee

tahereh saberi

reza zadmard

abstract

substituted naphthofurans and naphthopyrans were constructed at high temperature from allyl or propargyl naphthyl ethers via claisen rearrangement in moderate to good yields. also, substituted (trimethylsilyl)-naphthofurans were synthesized from the corresponding naphtofurans.

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A Novel Method for Synthesis of Substituted Naphthofurans and Naphthopyrans

Substituted naphthofurans and naphthopyrans were constructed at high temperature from allyl or propargyl naphthyl ethers via Claisen rearrangement in moderate to good yields. Also, substituted (trimethylsilyl)-naphthofurans were synthesized from the corresponding naphtofurans.

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A NOVEL METHOD FOR SYNTHESIS OF NAPHTHOFURANS AND NAPHTHODIFURANS

Thermal rearrangement of propargyl naphthyl ethers produced naphthopyrans. In the presence of sodium methoxide, propargyl naphthyl ethers were converted easily to naphthofurans and naphthodifurans in good yields

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A Novel Method for the Synthesis of 2-Ketomethylquinolines

Several 2-ketomethylquinolines were synthesized by heating, 2-methyl quinoline with acyl chloride in the presence of AlCl3 Contrary to reported procedures, this method was accomplished at a short time obtaining good results.

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Journal title:
iranian journal of chemistry and chemical engineering (ijcce)

Publisher: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

volume 16

issue 2 1997

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